Safety Data Sheet
(REACH Regulation (EC) N° 1907/2006 - N° 453/2010)

Effective Date: March 30, 2017

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name: 100-SL
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Manufacturing of a fixed or removable dental prosthesis in a dental laboratory
1.3. Details of the supplier of the safety data sheet
Manufacturer:
Company name: Leach & Dllon Dental Alloys
Full address: 5855 Oberlin Drive, San Diego, CA 92121-4718. USA
Technical Service: 1-800-255-5095 Customer Care: 1-800-255-5095
Fax: 1-858-626-8686
E-mail address of competent person responsible for the SDS: info@l&d.com
1.4. Emergency telephone number
Emergency telephone number: Chemtrec: 1-703-741-6090 (collect calls accepted ‑ German and English)


SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification information
This product does not meet the classification criteria in (EC) N° 1272/2008 (CLP)
This product does not meet the labeling criteria stated in 67/548/EWG and 1999/45/EC
2.2. Label elements
Labeling is in accordance with (EC) No 1272/2008 (CLP Regulation). Label elements in the solid form which the product is marketed
2.3. Other hazards
EYES Contact with eyes may cause severe irritation and possible eye burns.
SKIN: May cause severe irritation and possible burns.
INGESTION: May cause gastrointestinal irritation with nausea, vomiting, and diarrhea.
INHALATION: May cause irritation and burns to the respiratory tract.
SILVER Absorption of silver compounds by ingestion, inhalation or through broken skin can cause argyria, a permanent bluish-grey discoloration of the skin, conjuctiva and mucous membranes. Generalized argyria develops after 2 to 25 years of exposure. There are no systematic effects or symptoms and no physical disability. Silver is considered an experimental equivocal tumorigenic agent by RTECS criteria.
INDIUM May cause fetal effects based upon animal studies. May cause lung damage and blood abnormalities. Target Organs: Blood, kidneys, liver, lungs.
RUTHENIUM The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.



PBT assesment
No data available

vPvB assessment
No data available


SECTION 3: Composition/information on ingredients

3.1. Substances
This product is not a substance ‑ This is not applicable
3.2. Mixtures
Ingredients:

METAL % SYMBOL CAS NO EC/EG NO ACGIH 8 HR TLV OSHA 8 HR PEL

PALLADIUM 53.965 Pd 7440-05-3 231-115-6 No data No data
SILVER 37.06 Ag 7440-22-4 231-131-3 0.01 mg/m3 0.1 mg/m3
RUTHENIUM <1 Ru 7440-18-8 231-127-1 No data No data
INDIUM <1 In 7440-74-6 231-180-0 0.1 mg/m3 0.1 mg/m3 TWA
LITHIUM <1 Li 7439-93-2 231-102-5 No data No data
TIN 8.5 Sn 7440-31-5 231-141-8 2 mg/m3 2 mg/m3

Note: % values are in weight percent and reflect nominal composition.

Note: 'x' denotes a content of less than one percent



SECTION 4: First aid measures

4.1. Description of first aid measures
EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids.
SKIN CONTACT: Scrub skin thoroughly with soap and water.
If victim is conscious and alert, give 2-4 cupfuls of milk or water
INGESTION: If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Induce vomiting. **Never give anything by mouth to an unconscious person. Get medical aid.
INHALATION: Remove affected person to fresh air and assist with additional oxygen if necessary. Get first aid if other symptoms appear.

4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5: Fire-fighting measures

5.1. Extinguishing media
Metal fire powders, sand
5.2. Special hazards arising from the substance or mixture
Heating Beyond the melting range may generate fumes which are not flammable
5.3. Advice for fire-fighters
Wear protective clothing and use a self-contained breathing apparatus


SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Use proper personal protective equipment as described in section 8.
For emergency responders
Use proper personal protective equipment as described in section 8.
6.2. Environmental precautions
Collect contaminated materials in separate containers. Discharge according to local regulations.
6.3. Methods and material for containment and cleaning up
Avoid creating dust and pick-up using mechanical means
6.4. Reference to other sections
No data available


SECTION 7: Handling and storage

7.1. Precautions for safe handling
Ensure the workspace has proper ventilation
Do not consume substances during work.
General protective and hygiene measures
Wash hands before and after breaks. Remove contaminated clothing immediately. Do not ingest, or allow to come into contact with the eyes.
7.2. Conditions for safe storage, including any incompatibilities
Keep container closed in a ventilated area
7.3. Specific end use(s)
No data available


SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limit values
8.2. Exposure controls
RESPIRATORY: RESPIRATORY: Provide general ventilation and local exhaust to keep levels below the TLV stated in SECTION 3. Wear a NIOSH approved respirator for dust exceeding the TLVs.
Latex gloves are recommended while grinding, heat resistant gloves should be worn while casting and handling hot metals or molds.
EYE PROTECTION: Wear eye protection suitable to each individual operation.
OTHER: Wear apron, lab coat or other protective clothing.


SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance: WHITE
Odor: Not Applicable
pH: Not Applicable
Boiling Point: Not Applicable
Melting Range: 1180-1280 °C
Flash Point: Not Applicable
Flammability: Not Applicable
Autoflammability: Not Applicable
Explosive Properties: Not Applicable
Oxidizing Properties: Not Applicable
Vapor Pressure: Not Applicable
Solubility(Water/Fat): Insoluble
9.2. Other information
No data available



SECTION 10: Stability and reactivity

10.1. Reactivity
At ordinary and high (below the melting range) temperatures, the material oxidizes but is stable. At very high temperatures the alloy produces fumes.
10.2. Chemical stability
Product is stable under normal storage and handling conditions. See Section 7.
10.3. Possibility of hazardous reactions
Hydrogen gas can possibly form if the product comes into contact with acid
10.4. Conditions to avoid
N/A if the product is handled according to the Instructions for Use
10.5. Incompatible materials
Acid
10.6. Hazardous decomposition products
None are known


SECTION 11: Toxicological information

11.1. Information on toxicological effects
No data is available other than the information provided in Sections 2 and 3


SECTION 12: Ecological information

12.1. Toxicity
No data available
12.2. Persistence and degradability
No data available
12.3. Bio-accumulative potential
No data available
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
No data available
12.6. Other adverse effects
No data available


SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product:
Always recover all waste material and send to Department A at The Argen Corporation for refining.
Packaging:
Empty container completely and dispose according to local regulations.


SECTION 14: Transport information

14.1. Transport ADR/RID/AND
This product is not subject to ADR/RID/AND regulations
14.2. Transport IMDG
This product is not subject to IMDG regulations
14.3. Transport ICAO-TI / IATA
This product is not subject to ICAO-Ti / IATA regulations
14.4. Other information
No data available
No data available
14.5. Environmental hazards
No data is available other than the information provided in Sections 2 and 3
This product is not subject to ICAO-Ti / IATA regulations
14.6. Special precautions for user
none
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable


SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Germany:
Wassergefährdungsklasse WGK (VwVwS): WGK-1 (self-assessed)
15.2. Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.


SECTION 16: Other information

16.1. Training advice
In addition to health, safety and environmental training programs for their workers, companies must ensure that workers read, understand and apply the requirements of this SDS.
16.2. Disclaimer
The information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof. However, Leach & Dillon Dental Alloys makes no representations as to the completeness of accuracy thereof and information is supplied upon the condition that the persons receiving the above material will make there own determination as to its suitability for their purposes prior to use. In no event will "Leach & Dillon Dental Alloys" be responsible for damages of any nature whatsoever resulting from the use of or reliance upon information. No representations or warranties, either expressed or implied, or merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or the product to which information refers.